Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
A Novel Rate Enhancement in Titanium and Zirconium Alkoxide Mediated Cyano Group Transfers by the Addition of a Salycylal Type Schiff Base, dl-3-(2-Hydroxy-1-naphthylidene)-imino-ε-caprolactam. A Neighboring Amide Effect
Atsunori MoriShohei Inoue
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1991 Volume 20 Issue 1 Pages 145-148

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Abstract

The addition of a salycylal type Schiff base containing amide, dl-3-(2-hydroxy-1-naphthylidene)-imino-ε-caprolactam (Nap-ACL) to titanium (IV) 2-propoxide or zirconium (IV) 1-propoxide accelerates cyano group transfers of acetone cyanohydrin with various carbonyl and imino compounds to give the corresponding cyanated products.

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© 1991 The Chemical Society of Japan
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