Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Catalytic Activity for NO Decomposition of Cobalt Tetrapropoxyphthalocyanine Supported on Titania
Hiroshi FujitsuToshiaki SakakiharaIsao Mochida
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1991 Volume 20 Issue 1 Pages 159-162

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Abstract

Cobalt-tetrapropoxyphthalocyanine, CoPc(OPr)4, impregnated with THF onto TiO2 provided an anion radical (g value: 2.003) which gave a stationary NO(500 ppm) conversion of 27% in a flow reaction without oxygen at 423 K. Oxygen in the reactant gas increased the conversion to 55%, which decreased gradually to the stationary 27% without any formation of NC2 or CC2.

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© 1991 The Chemical Society of Japan
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