Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Evidences for Bromo-Bridged One-Dimensional Chain Structure of the Mixed-Valence Gold Complexes with the Empirical Formulas, [AuBr2(DBS)] and [AuBrCl(DBS)] (DBS = dibenzyl sulfide)
Kazuhiro TakahashiHiroshi Tanino
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1991 Volume 20 Issue 11 Pages 1977-1980

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Abstract

The bromo-bridged one-dimensional chain structure of [AuBr2(DBS)] is revealed by X-ray analysis. The bromo-bridged skeleton of the one-dimensional chain of [AuBrCl(DBS)] is identified by comparing its unit cell parameters, visible absorption spectrum on nujol mull, and Br K near-edge X-ray absorption spectra with those of [AuBr2(DBS)].

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© 1991 The Chemical Society of Japan
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