Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Detrapped Valence State of Iron(II)-Iron(III) Complexes with Carboxylic Acid
Yonezo MaedaYuichi TanigawaShinya HayamiYoshimasa Takashima
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1992 Volume 21 Issue 4 Pages 591-594

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Abstract

Diiron(II)-(III) complexes [Fe2L(pa)2](ClO4)2 and [Fe2L(mpdp)](ClO4)2 were prepared, where HL represents 2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-methylphenol, Hpa is pelargonic acid and H2mpdp is m-phenylenedipropionic acid. The valences of the irons are localized at low temperature, and delocalized in the Mössbauer time scale (1 × 10−7s) above 265 K for both of the complexes.

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© 1992 The Chemical Society of Japan
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