Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Pair-Selective Coupling of Alkynes with Alkenes on Zirconocene Complex
Tamotsu TakahashiZhenfeng XiChristophe J. RoussetNoriyuki Suzuki
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1993 Volume 22 Issue 6 Pages 1001-1004

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Abstract

When ethylene and alkynes such as 4-octyne and diphenylacetylene were treated with Cp2ZrBu2 highly pair selective coupling products were formed in high yields. Similarly, styrene or trimethylvinylsilane also afforded cross coupling products with alkynes on zirconocene complex.

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© 1993 The Chemical Society of Japan
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