1993 Volume 22 Issue 6 Pages 1049-1052
A series of dinuclear manganese(II) complexes [R1-LMn2(R2CO2)]ClO4 were synthesized and X-ray crystal structure analysis of [CH3-LMn2(CH3CO2)]ClO4 (1) was performed. Two manganese ions of 1 were six-coordinate with highly deformed octahedral structure. Electrochemical measurements of these complexes revealed that both the substituents of the phenol ring and those on the ligating acetate effectively control the redox properties of the Mn(II) center.
This article cannot obtain the latest cited-by information.