Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Synthesis and Electrochemical Properties of Dinuclear Manganese(II) Complexes with Octadentate Schiff-base Macrocycles. Fine Tuning of the Redox Behavior
Yoshiya IkawaToshi NagataKazuhiro Maruyama
Author information
JOURNALS RESTRICTED ACCESS

1993 Volume 22 Issue 6 Pages 1049-1052

Details
Abstract

A series of dinuclear manganese(II) complexes [R1-LMn2(R2CO2)]ClO4 were synthesized and X-ray crystal structure analysis of [CH3-LMn2(CH3CO2)]ClO4 (1) was performed. Two manganese ions of 1 were six-coordinate with highly deformed octahedral structure. Electrochemical measurements of these complexes revealed that both the substituents of the phenol ring and those on the ligating acetate effectively control the redox properties of the Mn(II) center.

Information related to the author

This article cannot obtain the latest cited-by information.

© 1993 The Chemical Society of Japan
Previous article Next article
feedback
Top