Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Rearrangement of 1-Alkynylcyclopropanol to 3-Substituted 2-Cyclopentenone Promoted by a Catalytic Amount of Octacarbonyldicobalt-Triphenylphosphite
Nobuharu IwasawaTakeshi Matsuo
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1993 Volume 22 Issue 6 Pages 997-1000

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Abstract

The rearrangement of 1-(1-alkynyl)cyclopropanols is catalyzed efficiently by the combined use of octacarbonyldicobalt and triphenylphosphite to give 3-substituted 2-cyclopentenones in high yields.

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© 1993 The Chemical Society of Japan
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