Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Production of Hydrogen Peroxide and Organic Hydroperoxides in the Reactions of Ozone with Natural Hydrocarbons in Air
Shiro HatakeyamaHaiping Laishidong GaoKentaro Murano
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1993 Volume 22 Issue 8 Pages 1287-1290

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Abstract

Reaction of ozone with three kinds of olefins in air was studied. H2O2, CH3OOH, and HOCH2OOH were collected and analyzed with HPLC with a fluorometric detector. Direct reaction of CH2OO with H2O was found to be the source of HOCH2OOH. CH3OOH was formed only from the olefins which have a methyl group. Detailed reaction mechanisms are discussed.

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© 1993 The Chemical Society of Japan
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