Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Extraordinary Diastereoselectivity Coupled to Altered Structure of Dipeptide Esters
Yoko MatsumotoYoshito MatsumotoJunichi InoueRyuichi Ueoka
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1993 Volume 22 Issue 8 Pages 1303-1304

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Abstract

The diastereoselectivity for the hydrolysis of Z-D(L)-Phe-L-Phe p-methoxycarbonylphenyl ester was maximized (ksDL/ksLL = 34) at the optimum temperature (30 °C). This could be attributed to the conformational change in the DL isomer, which was supported by the circular dichroism measurements.

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© 1993 The Chemical Society of Japan
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