Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Photo-response of the [Ru(bpy)3]2+ / BrO3 / H+ System in a Continuous-Flow Stirred Tank Reactor
Tetsuo SekiguchiYoshihito MoriIchiro Hanazaki
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1993 Volume 22 Issue 8 Pages 1309-1312

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Abstract

Effect of photo-irradiation on the autocatalytic oxidation of [Ru(bpy)3]Cl2 by acidic bromate has been investigated in a continuous-flow stirred tank reactor. The photo-induced bifurcation structure and phase diagram have been determined. It is shown that, for a certain range of the bromate concentration, the photo-irradiation can either promote or inhibit the autocatalytic oxidation of [Ru(bpy)3]2+ depending on the irradiation light power.

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© 1993 The Chemical Society of Japan
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