Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
N2-Binding Mononuclear Ruthenium(II) Tertiary Polyamine Complex by Direct Action of Gaseous Nitrogen in Aqueous Solution
Toshikazu TakahashiKazuhisa HirataniEiichi Kimura
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1993 Volume 22 Issue 8 Pages 1329-1332

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Abstract

Tertiary polyamine ruthenium(III) complex trans-[RuCl2(L)]+ (L = 2,5,9,12-tetramethyl-2,5,9,12-tetraazatridecane) has been prepared which can react with Mg and an atmospheric N2 gas in aqueous solution at room temperature to yield the first N2-binding ruthenium(II) tertiary polyamine complex trans-[RuCl(L)(N2)]+ that is converted into trans-[Ru(OH)(L)(N2)]+ and trans-[Ru(L)(N2)(OH2)]2+.

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© 1993 The Chemical Society of Japan
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