Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Structure and Electrical Properties of MeDTET Salts
Yohji MisakiHiroyuki NishikawaTokio YamabeTakehiko MoriHiroo InokuchiHatsumi MoriShoji Tanaka
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1993 Volume 22 Issue 8 Pages 1341-1344

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Abstract

Several cation radical salts of MeDTET (2-isopropylidene-1,3-dithiolo[4,5-d]ethylenedithiotetrathiafulvalene) showed metallic temperature dependence of conductivity down to 0.6–0.9 K. X-Ray crystal structure of (MeDTET)3PF6TCEx revealed that the donors have “κ-type” arrangement in the conducting sheet. This is the first example of a κ-type salt that has a composition other than 2:1.

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© 1993 The Chemical Society of Japan
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