Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Porphyrins Coupled with Nucleoside Bases. Synthesis and Characterization of Ether-Linked Adenine-Thymine and Guanine-Cytosine Derivatives
Masao HisatomeKoichi IkedaShusuke KishibataKoji Yamakawa
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1993 Volume 22 Issue 8 Pages 1357-1360

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Abstract

Porphyrins having an adenine-thymine or guanine-cytosine pair have been synthesized. Spectroscopic study has revealed that the two nucleobases form inter- and intramolecular base pairs in anti and syn atropisomers, respectively, and that the guanine-cytosine pair is more close to the porphyrin ring than the adenine-thymine pair.

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© 1993 The Chemical Society of Japan
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