Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Crystal Structures and Magnetic Properties of the p-N-Methypyridinium Nitronyl Nitroxide Cation Radical Salts, p-MPYNN·I and p-MPYNN·ClO4
Akira YamaguchiKunio AwagaTamotsu InabeTakayoshi NakamuraMutsuyoshi MatsumotoYusei Maruyama
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1993 Volume 22 Issue 8 Pages 1443-1446

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Abstract

X-Ray crystal analyses and magnetic measurements have been carried out on the p-N-methylpyridinium α-nitronyl nitroxide (p-MPYNN) cation radical salts, p-MPYNN·I and p-MPYNN·ClO4. The p-MPYNN molecules are connected by short intermolecular contacts between the NO groups in the crystal of p-MPYNN·I, while the radical molecules are separated from each other by the ClO4 anions in p-MPYNN·ClO4. The magnetic properties of p-MPYNN·I and p-MPYNN·ClO4 are found to be consistent with their crystal structures.

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© 1993 The Chemical Society of Japan
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