Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Synthesis of σ−π Conjugated Alternating Silylene-Diacetylene Copolymers and Their Optical and Electrical Properties
Mao-Ching FangAkira WatanabeMinoru Matsuda
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1994 Volume 23 Issue 1 Pages 13-16

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Abstract

New σ-π conjugated alternating silylene-diacetylene copolymers, –[(SiMe2)m–C≡C–C≡C]n–, m = 1, 3, 4, and 6, were synthesized by the reaction of α,ω-dichloropermethylated oligosilanes with dilithiobutadiyne, LiC≡C–C≡CLi. The IR spectra clearly indicated the presence of diyne unit in the polymer backbone. The influence of the chain length m of the dimethylsilylene unit in the –[(SiMe2)m–C≡C–C≡C]n– backbone on the optical and the electrical properties was investigated.

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© 1994 The Chemical Society of Japan
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