Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Novel Catalytic Metathesis of Substituted Olefins Promoted by Rhenium(I) Enolate Complexes
Masafumi HiranoMiwa HiraiYuji ItoAtsushi FukuokaSanshiro Komiya
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1994 Volume 23 Issue 1 Pages 165-166

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Abstract

Rhenium(I) enolate complexes Re(NCCHCO2Et)[NC(EtO2C)C=CHPh](PMe2Ph)4 and Re(NCCHCO2Et)(NCCH2CO2Et)(PMe2Ph)4 are found to catalyze unique olefin metathesis reaction of tetracyanoethylene with ethyl α-cyanocinnamate to give 1,1 dicyano-2-phenylethylene and ethyl 2,3,3-tricyanopropenoate at room temperature.

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© 1994 The Chemical Society of Japan
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