Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Photolysis of trans(t-N,S)-[Co{S(O)2CH2COO-S,O}(tren)]+ (t-N = tertiary amine nitrogen; tren = tris(2-aminoethyl)amine). Linkage and Geometrical Isomerization
Farooque MD. AkhterMasaaki KojimaToshihito YoshiiSetsuo KashinoYuzo Yoshikawa
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1994 Volume 23 Issue 1 Pages 171-174

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Abstract

On photolysis of trans(t-N,S)-[Co{S(O)2CH2COO-S,O}(tren)]+ with visible light, both linkage isomerization (sulfinato-S to sulfinato-O) and geometrical isomerization (trans to cis) took place to yield cis(t-N,O(S))- and trans(t-N,O(S))-[Co{OS(O)CH2COO-O,O}(tren)]+ (O(S) = oxygen of sulfinate group).

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© 1994 The Chemical Society of Japan
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