Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Nuclear Magnetic Resonance Spectroscopic Study on the Grafting of Ethylene Oxide onto the Interlayer Surface of γ-Zirconium Phosphate
Hideyuki NakanoTakeshi OhnoShoji Yamanaka
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1994 Volume 23 Issue 1 Pages 9-12

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Abstract

The reaction products of γ-zirconium phosphate with ethylene oxide were analyzed by solid-state 31P magic-angle spinning (MAS) NMR, and 31P and 13C solution NMR spectroscopy. γ-Zirconium phosphate can be formulated as Zr(PO4)(H2PO4)·2H2O. Ethylene oxide molecules react with the interlayer H2PO4 groups, forming diester derivatives of ethylene and/or diethylene glycols.

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© 1994 The Chemical Society of Japan
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