Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Activation of Methane Promoted by NeohexylPt(II) Complexes. Isolation of MethylPt(II) Complexes
Akira MiyashitaYoshiko Saida
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1994 Volume 23 Issue 12 Pages 2263-2266

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Abstract

trans-Pt(CH2CMe2Et)Br(PPh3)2 induced C-H bond activation of CH4 under UV p irradiation leading to trans-PtMeBr(PPh3)2, while H-D exchange reaction of CH4 with D2 or D2SO4 took place in the photochemical reaction system containing Pt(PPh3)4 and neohexyl bromide. A possible reaction mechanism involving radical process is discussed on the basis of radical-trap experiment.

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© 1994 The Chemical Society of Japan
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