Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Enzymatic Bromo-ether Cyclization of Laurediols with Bromoperoxidase
Akio FukuzawaMya AyeYasunori TakasugiMasao NakamuraMamoru TamuraAkio Murai
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1994 Volume 23 Issue 12 Pages 2307-2310

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Abstract

Natural (3E,6R,7R)- and (3Z,6S,7S)-laurediols were subjected to enzymatic reaction with the partially purified bromoperoxidase from the red alga, Laurencia nipponica, in the presence of H2O2 and NaBr to afford laurencin and prelaureatin, respectively. The further reaction of these products with bromoperoxidase gave rise to the bicyclic bromo-ethers.

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© 1994 The Chemical Society of Japan
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