Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Total Synthesis of (−)-Cotylenol, a Fungal Metabolite Having a Leaf Growth Activity
Hiroaki OkamotoHiroaki AritaNobuo KatoHitoshi Takeshita
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1994 Volume 23 Issue 12 Pages 2335-2338

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Abstract

Cotylenol, one of the representative fusicoccane diterpenoids having 5-8-5-membered tricyclic carbon framework, is now synthesized for the first time via an eight-membered ring formation by an intramolecular ene reaction followed by an oxidative formation of the 8β,9α-glycol function on the central eight-membered ring.

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© 1994 The Chemical Society of Japan
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