Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Reactions of Alkyl malonates with Molybdenum and Tungsten Complexes. Syntheses and Structure of Hydrido-Malonato Complexes
Makoto MinatoSusumu KurishimaKo-ichiro NagaiMikio YamasakiTakashi Ito
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1994 Volume 23 Issue 12 Pages 2339-2342

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Abstract

Molybdenum and tungsten hydrido-malonato complexes have been prepared by the photochemical or thermal reactions of [MoH4(dppe)2] or trans-[W(N2)2(dppe)2] with an excess of alkyl malonates. The structure of the complex is reported, and a possible mechanism is proposed for the reaction.

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© 1994 The Chemical Society of Japan
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