Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
An Efficient Triple Allylation of 1,3,5-Triazine by Means of Tin Reagent. Facile Synthesis of syn,syn-2,4,6-Trifunctionalized 1,3,5-Triazacyclohexanes
Ryohei YamaguchiSeiichi KobayashiSinpei Kozima
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1994 Volume 23 Issue 12 Pages 2349-2352

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Abstract

An efficient triple addition of allyl groups to 1,3,5-triazine has bee carried out by means of an allyltin reagent to give 2,4,6-trially-1,3,5-triazacyclohexanes in high yields. Epoxidation and hydroxylation of the syn,syn-stereoisomer afford geometrically interesting syn,syn-trifunctionalized 1,3,5-triazacyclohexane derivatives.

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© 1994 The Chemical Society of Japan
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