Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Organo-Rhodium Complex with Tridentate Biradical Ligand, [Rh(Cp*)(bisnitpy)](PF6)2
Hiroki OshioAkihiro OhtoJun’ichi FujisawaTakashi WatanabeTasuku ItoKiyoshi Isobe
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1994 Volume 23 Issue 12 Pages 2353-2356

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Abstract

A new Rh(III) complex, [Rh(Cp*)(bisnitpy)](PF6)2 (Cp* = η5-C5Me5 and bisnitpy = 2,6-bis(1′-oxyl-3′-oxido-4′,4′,5′,5′-tetramethyl-4′,5′-dihydro-1′H-imidazol-2′-yl)pyridine), has been prepared, which is the first example of organometallic complex having nitronyl nitroxide ligand. X-ray structure and magnetic property of the title complex are reported.

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© 1994 The Chemical Society of Japan
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