Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Palladium-Catalyzed Aminocarbonylation of Cinnamyl N,N-Dialkylcarbamates. An Intriguing Crossover with p-Methylcinnamylamines
Masahiro MiyazawaKeiji Yamamoto
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1994 年 23 巻 3 号 p. 491-494

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Competition experiments in the palladium-catalyzed aminocarbonylation of cinnamyl N,N-dialkylcarbamates with p-methylcinnamylamines revealed that the allylamine did not undergo oxidative addition but attacked extensively a π-allylpalladium which arose from the allyl carbamate under the conditions employed, forming a mixture of the corresponding amides containing either cinnamyl moiety that incorporates a dialkylamino component originated only from the carbamate.

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© 1994 The Chemical Society of Japan
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