Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Polysilane Synthesis by Catalytic Disproportionation of Alkoxydisilanes
Keiji KabetaShigeru WakamatsuTakafumi Imai
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1994 Volume 23 Issue 5 Pages 835-838

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Abstract

Network polysilanes with methyl, phenyl, and ethoxy groups (Mw 530–7000) were prepared by a catalytic disproportionation reaction of methylethoxydisilanes in the presence of phenylethoxysilanes. Hexyl or cyclohexyl groups were also incorporated into polysilanes when corresponding alkoxysilanes were employed. Reaction of pentamethylethoxydisilane clarified a mechanism of the reaction.

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© 1994 The Chemical Society of Japan
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