Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Reactions of Selenurane [10-Se-4 (C4)] with Alcohols, Thiols and Selenol. A Quest for Formation of a New a-Selenurane [10-Se-4 (C3O)], [10-Se-4 (C3S)] or [10-Se-4 (C3Se)]
Soichi SatoNaomichi Furukawa
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1994 Volume 23 Issue 5 Pages 889-892

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Abstract

Bis(2,2′-biphenylylene)selenurane readily reacts with various alcohols, phenols, thiols and selenol to give ligand coupling or ipso-substitution products under mild conditions via a two-step mechanism involving a σ-selenurane [10-Se-4 (C3O)], [10-Se-4 (C3S)] and [10-Se-4 (C3Se)] or corresponding selenonium salts as intermediates.

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© 1994 The Chemical Society of Japan
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