Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Interaction between CO2 and Electrochemically Reduced Species of N-propyl-4,4′-bipyridinium Cation
Hitoshi IshidaTomoyuki OhbaTomohiro YamaguchiKatsutoshi Ohkubo
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1994 Volume 23 Issue 5 Pages 905-908

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Abstract

The one-electron reduced species of N-propyl-4,4′-bipyridinium cation (1+) which is generated under electrolysis at −1.1 V vs. SCE was found to be able to react with CO2 although it is even a neutral radical. The intermediate CO2 adduct was furthermore reduced by one-electron at the same electrolysis potential to form a stable CO2 adduct.

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© 1994 The Chemical Society of Japan
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