Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Reactivity of Cation Radicals Generated from Trivalent-Phosphorus Compounds in the Reaction with Methylviologen: Kinetic Analysis
Shinro YasuiKosei ShiojiMunekazu TsujimotoAtsuyoshi Ohno
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1995 Volume 24 Issue 9 Pages 783-784

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Abstract

Cation radicals generated from trivalent-phosphorus compounds through single-electron transfer to methylviologen undergo ionic reactions with alcohols or thiols. A kinetic analysis of the reactions has suggested that the reaction of the trivalent-phosphorus cation radicals with alcohols possesses a tighter transition state than that with thiols.

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© 1995 The Chemical Society of Japan
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