Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Substituent-Dependent Selective Replacement of Alkyne Moieties of Zirconacyclopentadienes via C-C Bond Cleavage Reaction
Ryuichiro HaraZhenfeng XiMartin KotoraChanjuan XiTamotsu Takahashi
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1996 Volume 25 Issue 11 Pages 1003-1004

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Abstract

Replacement of an alkyne moiety of zirconacyclopentadienes via β,β′-carbon-carbon bond cleavage was highly dependent on their substituents. Complete differentiation between diphenylacetylene and 4-octyne in the reaction with butyronitrile was demonstrated.

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© 1996 The Chemical Society of Japan
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