Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
ESR Studies on Poly(methyl acrylate) Radicals to Estimate Their Dominant Structure
Yoshio Sugiyama
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1996 Volume 25 Issue 11 Pages 951-952

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Abstract

Electron Spin Resonance (ESR) examinations of the propagating radicals in the polymerization of methyl acrylate (MA) and methyl acrylate-α-d (MA-d) in the frozen state have been made. Selective deuteration of MA showed that the propagating radicals have the chain-end (I) and not the mid-chain (II) structure. The stable conformation of poly (methyl acrylate) (poly (MA)) radical was also determined.

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© 1996 The Chemical Society of Japan
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