Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Double Mediatory System Involving a Flavin Analog and a p-Benzoquinone Derivative for Photoinduced Electrochemical Oxidation of Benzyl Alcohol to Benzaldehyde in Acetonitrile
Masashi IshikawaHiroyuki OkimotoMasayuki MoritaYoshiharu Matsuda
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1996 Volume 25 Issue 11 Pages 953-954

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Abstract

The photoinduced electrochemical oxidation of benzyl alcohol to benzaldehyde in acidic acetonitrile proceeded with practically 100% product selectivity and ca. 100% current efficiency under visible-light irradiation in the presence of riboflavin-2′,3′,4′,5′-tetraacetate (RF) as a mediator. A double mediatory system involving duroquinone as well as RF resulted in remarkable acceleration of the benzaldehyde formation with maintenance of both the high product selectivity and high current efficiency.

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© 1996 The Chemical Society of Japan
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