Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
A Stereoregular Polyphenylacetylene Derivative Bearing an Amino Group as a Probe for Chirality Assignments of Acids by Circular Dichroism
Eiji YashimaYukio MaedaYoshio Okamoto
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1996 Volume 25 Issue 11 Pages 955-956

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Abstract

Cis-transoidal poly(4-(N,N-diisopropylaminomethyl)phenylacetylene) prepared by polymerization with [Rh(nbd)Cl]2 was found to exhibit an induced circular dichroism in the UV-visible region upon complexation with optically active acids probably due to a prevailing one-handed helix formation of the polymer, the sign of which reflects the absolute configuration of the acids.

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© 1996 The Chemical Society of Japan
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