Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
1,4-Asymmetric Induction from Chiral δ-Oxygenated Allylic Tin Reagents
Yutaka NishigaichiMiyuki YoshikawaYasuyo TakigawaAkio Takuwa
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1996 Volume 25 Issue 11 Pages 961-962

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Abstract

A new type of asymmetric induction from allylic tin reagents is developed. A chiral allylic tin which has an oxygen substituent (ether or ester) at its δ-position successfully induces a new chirality in a 1,4-induction mode in the reaction with aldehydes via the transmetallation with SnCl4.

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© 1996 The Chemical Society of Japan
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