Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Catalytic Dehydrochlorination of 1, 2-Dichloroethane over Pyridine Deposited Pitch-Based Active Carbon Fiber
Chiaki SotowaYuji KawabuchiIsao Mochida
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1996 Volume 25 Issue 11 Pages 967-968

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Abstract

Pitch-based active carbon fiber (pitch-ACF) modified by pyridine chemical vapor deposition (CVD) showed excellent catalytic activity for dehydrochlorination of 1, 2-dichloroethane (1, 2-DCE) into vinyl chloride (VC). Compared with polyacrylonitrile-based ACF (PAN-ACF), the present ACF of 2% weight increase by CVD showed long life over 300 h at 360 °C (conversion: ca. 20%; VC selectivity: 99.7%; contact time: 5.8 × 10−3).

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© 1996 The Chemical Society of Japan
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