Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Stereoselective Synthesis of ABC-Ring System of Hemibrevetoxin B
Hiroko MatsukuraMasamichi MorimotoTadashi Nakata
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1996 Volume 25 Issue 6 Pages 487-488

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Abstract

The 6, 6, 7-membered tricyclic ether ring system (ABC-ring) of hemibrevetoxin B was stereoselectively synthesized. The curcial steps in the present synthesis involve the ring expansion of tetrahydropyran to oxepane, 6-endo cyclization of epoxy alcohol, and insertion of a C-4 unit to the A-ring.

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© 1996 The Chemical Society of Japan
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