Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Trinuclear Cobalt(III) Complex Having Partial Cubane Co3O4 Core: Synthesis and Structural Analysis of the Complex Containing Bis(2-pyridylmethyl)amine
Tomoharu AmaKen-ichi OkamotoToshiaki YonemuraHiroshi KawaguchiYoshiko OgasawaraTakaji Yasui
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1997 Volume 26 Issue 1 Pages 29-30

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Abstract

The trinuclear cobalt(III) complex with the partial cubane Co3O4 core, [Co3(dpa)3(μ-OH)33-O)]4+ (dpa: bis(2-pyridylmethyl)amine), was prepared and the structure was determined by the X-ray diffraction method. Though the partial cubane structure was slightly distorted by the N–H↔H–N repulsive interaction, this complex is stable at least 5 days in its neutral aqueous solution.

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© 1997 The Chemical Society of Japan
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