Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Electrochemical Syntheses and Electrochromic Properties of Chromium Cyanide Magnetic Thin Films
Osamu SatoZhongze GuHiroyuki EtohJun-ichi IchiyanagiTomokazu IyodaAkira FujishimaKazuhito Hashimoto
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1997 Volume 26 Issue 1 Pages 37-38


Electrochemical preparation method and electromic properties of the mixed valence chromium cyanide thin film, which is one of the ferrimagnet with highest critical temparature (Tc) among molecule-based magnets, were described. The difference in the ability of the ligand substitution reaction between CrII and CrIII was utilized to synthesize the prussian blue analogs. The obtained magnetic material exhibited an excellent electrochromic properties. This indicates the compound has a potential for future display devices, as well as tunable molecule-based magnetic devices.

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© 1997 The Chemical Society of Japan
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