Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
A Novel Dinuclear Iridium(III) Complex with a Bridging Disulfide Bond. Conversion of Coordinated Thiolato to Coordinated Bridging Disulfide by Acid Oxidation
Takumi KonnoYoshitaro MiyashitaKen-ichi Okamoto
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1997 Volume 26 Issue 1 Pages 85-86

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Abstract

Treatment of fac(S)-[Ir(aet)3] (aet = 2-aminoethanethiolate) with acid in water gave a novel dinuclear Ir(III) complex, [Ir2(aet)4(cysta)]2+ (cysta = cystamine), in which two octahedral Ir(III) units are linked by a coordinated disulfide bond.

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© 1997 The Chemical Society of Japan
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