Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Novel Concurrent Formation of Mo–Si and Si–C Bonds by the Reaction between [MoH4(Ph2PCH2CH2PPh2)2] and PhSiH3
Da-Yang ZhouMakoto MinatoTakashi ItoMikio Yamasaki
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1997 Volume 26 Issue 10 Pages 1017-1018

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Abstract

Reaction of [MoH4(Ph2PCH2CH2PPh2)2] with PhSiH3 in refluxing toluene yielded doubly chelated novel complexes with the Si–C–C–P–Mo framework as a result of the oxidative addition involving Si–H bond cleavage concurrent with the selective activation of the ortho C–H bonds of the dppe ligands.

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© 1997 The Chemical Society of Japan
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