Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Lanthanide Triflate-Catalyzed Three-Component Coupling Reactions of Aldehydes, Hydroxylamines, and Alkenes Leading to Isoxazolidine Derivatives
Kobayashi ShuRyo AkiyamaMikako KawamuraHaruro Ishitani
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1997 Volume 26 Issue 10 Pages 1039-1040

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Abstract

Three-component coupling reactions of aldehydes, hydroxylamines, and alkenes proceeded smoothly in the presence of a catalytic amount of a lanthanide triflate, to afford isoxazolidine derivatives in high yields with high diastereoselectivities. The asymmetric 1,3-dipolar cycloaddition using a chiral lanthanide catalyst is also described.

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© 1997 The Chemical Society of Japan
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