Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Aerobic Oxidation of Cyclohexane Catalyzed by Fe(III)(5,10,15,20-tetrakis(pentafluorophenyl)porphyrin)Cl in Sub- and Super-Critical CO2
Xiao-Wen WuYoshito OshimaSeiichiro Koda
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1997 Volume 26 Issue 10 Pages 1045-1046

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Abstract

Aerobic oxidation of cyclohexane to yield cyclohexanol and cyclohexanone in the presence of a Fe-porphyrin catalyst bearing meso-pentafluorophenyl group and acetaldehyde has been efficiently enhanced in pressurized CO2. The reaction rate takes a maximum value in the neighborhood of critical pressure.

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© 1997 The Chemical Society of Japan
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