Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Mechanism of Cis-to-Trans One Way Isomerization of Stilbene and Formation of Its Stable Dimer Cation Radicals in Zeolite Cavities
Masanobu KojimaHaruhiko TakeyaYasunao KuriyamaShigero Oishi
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1997 Volume 26 Issue 10 Pages 997-998

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Abstract

Cis-to-trans one way isomerization of stilbene in the first case catalyzed by proton, and then, secondly through electron transfer, occurred in acidic zaolites without light, suggesting that dimer cation radicals with charge transfer interaction between trans-stillbene and its cation radical may be formed in H-ZSM-5, whereas 1,4-dimer cation radicals of stilbene may be produced in H-mordenite.

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© 1997 The Chemical Society of Japan
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