Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
1,4-Asymmetric Induction in Palladium(II)-catalyzed Intramolecular N-Alkylation Reaction. Construction of 2-Functionalized 5- Hydroxypiperidine
Yoshiro HiraiKaori ShibuyaYoko FukudaHajime YokoyamaSeiji Yamaguchi
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1997 Volume 26 Issue 3 Pages 221-222

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Abstract

Palladium(II)-catalyzed cyclization of optically active urethanes containing an allylic alcohol moiety was examined. Efficient 1,4-asymmetric induction was found in this reaction. The cycloadducts were converted to pseudoconhydrine.

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© 1997 The Chemical Society of Japan
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