Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
99Ru-NMR Spectroscopy of Ruthenium(II) Tris-Polypyridine Complexes
Xiao XiaomingTakeko Matsumura-InoueShigeo Mizutani
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1997 Volume 26 Issue 3 Pages 241-242

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Abstract

The 99Ru-NMR spectra of a series of tris-polypyridine ruthenium(II) complexes were studied in acetonitrile solution. The spectroscopic results indicate that the 99Ru-NMR chemical shifts of these complexes are sensitive to the environment around the metal center. The correlation between the 99Ru-NMR chemical shifts and the energy of metal-to-ligand charge transfer, EMLCT, was discussed.

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© 1997 The Chemical Society of Japan
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