Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Second-Order Hyperpolarizability of Pyridinium Cations
AnwarXuan-Ming DuanKyoji KomatsuShuji OkadaHiro MatsudaHidetoshi OikawaHachiro Nakanishi
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1997 Volume 26 Issue 3 Pages 247-248

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Abstract

The second-order hyperpolarizability (β) of pyridinium cations with cutoff (λco) shorter than 400 nm were studied by semiempirical calculation and the hyper-Rayleigh scattering (HRS) technique. The β value of 4-dimethylaminopyridinium (λco=390 nm) was evaluated to be about 1.5 times larger than that of p-nitroaniline (λco=473 nm) in methanolic solution using 1064 nm light as a fundamental beam.

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© 1997 The Chemical Society of Japan
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