Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Synthesis of Benzene from Methane and Carbon Monoxide over Silica-Supported Rh, Ru and Pd Catalysts
Shuichi NaitoTadahiko KarakiToshiaki Iritani
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1997 Volume 26 Issue 9 Pages 877-878

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Abstract

Benzene was formed selectively among hydrocarbons produced in CH4-CO reaction over silica supported Rh, Ru and Pd catalysts at 573-723 K under atmospheric pressures, although CO2 was the main product, which was formed by the disproportionation of CO. Addition of H2 to CH4-CO reaction accelerated the rate of benzene formation several times, and the selectivity increased considerably.

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© 1997 The Chemical Society of Japan
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