Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Titanocene Induced Deoxygenation of Di-epoxides - A Convenient Regioselective Preparation of 1,3-Diols
J. S. YadavDale Srinivas
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1997 Volume 26 Issue 9 Pages 905-906

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Abstract

Titanocene induced regioselective opening of 2,4-di-epoxy alcohols to 1-ene-3,5-diols is described. Diepoxy alcohols were treated with 3 eq. of Cp2TiCl in dry THF to obtain 1-ene-3,5 diols with conservation of stereochemistry at C-3 and C-5 was observed.

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© 1997 The Chemical Society of Japan
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