Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Porphyrin Architectures Constructed by CH···π Interactions: Synthesis and Crystal Structures of 5,10,15,20-Tetrakis(4-methylchalcogenophenyl)-21H,23H-porphyrins
Ken-ichi SugiuraKantaro UshirodaTakanori TanakaMasami SawadaYoshiteru Sakata
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1997 Volume 26 Issue 9 Pages 927-928

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Abstract

Tetraphenylporphyrins substituted with methylchalcogeno groups (XMe: X = Te, Se, S, and O) were prepared. Crystal structure analysis revealed that a novel type of molecular alignments was achieved by intermolecular CH···π interactions between XCH3 and porphyrin π-systems.

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© 1997 The Chemical Society of Japan
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