Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
A New Method for the Synthesis of Baccatin III
Isamu ShiinaHayato IwadareHiroki SakohMasatoshi HasegawaYu-ichirou TaniTeruaki Mukaiyama
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1998 Volume 27 Issue 1 Pages 1-2

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Abstract

Baccatin III was efficiently synthesized from the BC ring system of Taxol,2α,10β-dibenzyloxy-11β-(t-butyldimethylsil-oxy)-7β-hydroxy-1α-(4-methoxybenzyloxy)-8β,15,15-trimethyl-4-methylene-trans-bicyclo[6.4.0]dodecan-9-one(1), by succes-sive constructions of A and D rings via respective intramolecular pinacol coupling and oxetane forming reaction.

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© 1998 The Chemical Society of Japan
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